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Wisconsin Water Quality Guide

Haloacetic Acids (HAA5) in Wisconsin Drinking Water

HAA5 is the other major disinfection byproduct — formed the same way as TTHMs when chlorine meets organic matter in your water supply.

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Federal limits and health goals

EPA legal limit (MCL)

0.060 mg/L

The federally enforceable maximum contaminant level. Above this, the system is in violation.

Health goal

1.0e-4 mg/L

A non-binding target representing minimal known risk over a lifetime of exposure.

What is haloacetic acids (haa5)?

A group of chemical byproducts formed during water disinfection. Regulated as a sum of five specific haloacetic acid compounds.

Health effects

Increased risk of cancer

Where it comes from

Byproduct of drinking water disinfection

Wisconsin context

HAA5 stands for five haloacetic acids: monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, monobromoacetic acid, and dibromoacetic acid. Like TTHMs, they form when chlorine disinfectant reacts with organic matter in source water. The EPA limit is 60 micrograms per liter as a Locational Running Annual Average. HAA5 and TTHMs are regulated under the same Stage 2 Disinfectants and Disinfection Byproducts Rule (Stage 2 DBPR), and systems that struggle with one usually struggle with both.

In Wisconsin, the geographic pattern mirrors TTHMs — smaller systems with high-organic source water in northern and southwestern counties see the highest levels. The Driftless Area and Northwoods are particularly affected. Unlike TTHMs, HAA5 is less volatile and doesn't evaporate as readily from hot water, so exposure from showering is lower. The primary exposure route is ingestion.

Filtration that helps

Treatment categories that can reduce haloacetic acids (haa5) in drinking water. Category-level only — no specific brands or models.

Granular Activated Carbon (GAC)

low cost

Activated carbon media that adsorbs organic contaminants, disinfection byproducts, chlorine, taste-and-odor compounds, and many volatile organic chemicals. Widely used as both a point-of-use cartridge and a whole-house (point-of-entry) tank.

Limitations: Not effective against nitrate, fluoride, heavy metals at typical residential contact times

Frequently asked questions

What's the difference between HAA5 and TTHMs?
They're both disinfection byproducts formed by the same chemical reaction (chlorine + organic matter), but they're different families of compounds. TTHMs include chloroform and related chemicals; HAA5 includes acetic acid derivatives. They have separate EPA limits (80 µg/L for TTHMs, 60 µg/L for HAA5) and are measured independently. A system can be over on one and under on the other.
Are haloacetic acids dangerous?
Dichloroacetic acid and trichloroacetic acid — two of the five HAA5 compounds — have been classified as possible human carcinogens based on animal studies. Long-term exposure above the EPA limit is associated with increased cancer risk. As with TTHMs, the risk is chronic, not acute — a single exposure isn't the concern, sustained daily intake over years is.
Does boiling water remove HAA5?
Partially. Some HAA5 compounds decompose at high temperatures, but boiling also concentrates the water, so the net effect is uncertain. Activated carbon filtration is more reliable. Unlike TTHMs, HAA5 doesn't off-gas readily, so running your tap or aerating the water doesn't help much.
Can my water utility do anything about HAA5?
Yes. Utilities can reduce HAA5 by removing organic matter before chlorination (enhanced coagulation), switching from free chlorine to chloramines (which produce fewer byproducts), optimizing the chlorine dose and contact time, or adding granular activated carbon treatment. Many Wisconsin systems have successfully reduced HAA5 through these approaches.

Curious about filtration for your home or facility?

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